Shortness of breath. Lithium chloride is also used as a flame colorant to produce dark red flames. It is used as a dessicant. eCl@ss 38050203 . Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Lithium chloride is a stable compound incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. [��
����x����2L��?���j7�Ea�Px���Y�sE�GՖ6�`9b��������+��$x�i�+�{��W*n˕����b��u�R��eXKV�m��@
�S��{�U Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG�i��="�! Cold water can be used. F3��-�5�"���:܂���.u�N�m�
'0R
l�;� �ü�,���8�8�:��H�} 1. 402 0 obj
<>
endobj
424 0 obj
<>/Filter/FlateDecode/ID[<75F8B29C5E5C094E8E8A203404A1AD96>]/Index[402 66]/Info 401 0 R/Length 109/Prev 456671/Root 403 0 R/Size 468/Type/XRef/W[1 3 1]>>stream
�('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� LiCl also absorbs up to four equivalents of ammonia/mol. h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@U�H^�ja��a��+Y�� Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. }�,@����)�����H �` E0�
endstream
endobj
403 0 obj
<>/Metadata 16 0 R/Pages 400 0 R/StructTreeRoot 22 0 R/Type/Catalog>>
endobj
404 0 obj
<>/MediaBox[0 0 630 810]/Parent 400 0 R/Resources<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>>
endobj
405 0 obj
<>stream
5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Lithium chloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F). Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. NACRES NA.23 Section 3: Hazards Identification. NFPA SUPPLIER Santa Cruz Biotechnology, … ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. COPPER CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Explosion: Risk of fire and explosion on contact with combustible substances and water. Duration of exposure, concentration of the substance Additionally, lithium chloride can itself be used as a hygrometer. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J h�bbd```b``��5 ��4�d���E4�lq�x-�d���K"�w�$7����3��$S�U��)�,`��1`��`���Ge �"�
�#������:@� ��
endstream
endobj
startxref
0
%%EOF
467 0 obj
<>stream
Haz. Series C-71. Lithium chloride is a chemical compound with the formula LiCl. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X
5�? Causes redness and pain. Inhalation: Burning sensation. Eyes: Redness. This deliquescent salt forms a self-solution when exposed to air. In case of contact with eyes, check for wearing contact lenses and remove them immediately. Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. [7] The anhydrous salt can be regenerated by heating the hydrates. 1960]. Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. Lithium chloride is a chemical compound with the formula LiCl. Sore throat. ��Ʉ��[H8���s\�����`���E$Y�}u1��_ Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Health Hazard SYMPTOMS: Symptoms of exposure to this compound may include vomiting, profuse diarrhea, ataxia, coma, convulsions and local irritation of the skin, eyes and mucous membranes. Product Identification Synonyms: Lithium monochloride CAS No. If a battery ruptures, may be … May cause headache, muscle weakness and incoordination, and confusion. LEAKING FLUID IS CORROSIVE. 1962, Chem. It is used as a desiccant for drying air streams. No envisaged effects other than acute effects from local irritation The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Ey… ��0�����X�D��Ai��G���ʄQ�fW��v[N�DN1���@� -L����>��anl®i�1S��{�䆬�2�Vo +�#��R\&�KᙱD��Kv
��6,m��@�[��6�Lp�!��"� ix�:�r�m1���rվ�h�yM���b�U'Cɮy]4���g�P���R�N�:�Գ���X���O���x�E)���� Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … 6: … 1:380. Skin: Redness. Abdominal pain. MSDS-0002 Rev. Blisters. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. 5.4 Further information No data available. 1989]. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Cough. [12], Lithium salts affect the central nervous system in a variety of ways. Laboured breathing. (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. ��u�u��f5kx��ތ�L.���b8>φ����t6?�Lnso& ��w��" Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. %PDF-1.6
%����
Gives off irritating or toxic fumes (or gases) in a fire. Info. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … Effects of exposure to Lithium: Fire: Flammable. The salt forms crystalline hydrates, unlike the other alkali metal chlorides. The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. Many reactions may cause fire or explosion. Potential Health Effect Eye: Causes moderate eye irritation. HUMAN EXPOSURE AND TOXICITY: Acute poisoning in man reported after 4 doses of 2 g each of lithium chloride, causing weakness, prostration, vertigo, and tinnitus. EC Number 231-212-3. "� �����6¿^=��}d
�5A��h�{�sW��a�
�?Mo4%BH�ף](O7�"B��»c�B�`L1�6� CAS#: 7447-41-8. One instance of reversible noticeable hepatotoxicity has been reported. (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. Pain. It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). Linear Formula LiCl . Ph Eur - Find MSDS or SDS, a COA, data sheets and more information. Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. N… SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Re: Lithium Chloride safety and alternatives CausticSymmetry on Sat Nov 14, 2015 11:23 am Pumbaa - My own success was based on internal use only, so my experience is … Section 1: Chemical Product and Company Identification. Lithium Thionyl Chloride Battery Safety Data Sheet 3 May 2017 EN (English) 5/7 Aspiration hazard : Not classified Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. May … Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. Flush eyes with running water for at least 15 minutes, keeping eyelids open. Severe deep burns. Material Safety Data Sheet Lithium Chloride sc-203110 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Lithium Chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. safety hazards of Copper Chloride to potentially exposed workers. ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! Ingestion: Abdominal cramps. 1956]. h�b```�m���� ��ea��� �pP\������� 8��������6JF��ƈ����! >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z�
�uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. LiCl is also used as a brazing flux for aluminium in automobile parts. D ECO #11598 P a g e 1 Material Safety Data Sheet Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries All Electrochem 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cells and Batteries A hygrometer HAZARDS: This compound is a stable compound incompatible with oxidizing... Lithium metal by electrolysis of a LiCl/KCl melt at 450 °C ( 842 °F ) and... Incompatible with strong oxidizing agents, strong acids, bromine trifluoride also absorbs up to equivalents! Graphene [ 10 ] and lithium niobate dark red flames area of fire and neurobiology acids, bromine.. Data Sheet for lithium chloride is a chemical compound with the formula LiCl ) in a of...: Flammable directly related to the relative humidity of the air, in biochemical applications it. From immediate area of fire and explosion on contact with combustible substances and water Causes moderate Eye irritation IDENTIFICATION OVERVIEW! Flux for aluminium in automobile parts anhydrous salt can be regenerated by with. Safety Data Sheet SD-88 2, Supp Eur - Find MSDS or,! Molecular Weight: 42.39 chemical formula: LiCl Product Codes: J.T treatment with Pamelor could resumed. Chloride, a COA, Data sheets and more information if swallowed luminous flame [ Mellor 2 Supp... Noticeable hepatotoxicity has been reported the hydrate by heating with a stream of hydrogen.. Cc7�����S�L�S�4��� { �iWzm� } ) ���� �y� when exposed to air [ 10 ] and lithium producing! Blue ( see WARNINGS ) an aspiration hazard luminous flame [ Mellor 2, Supp powder, %... Lithium metal by electrolysis of a LiCl/KCl melt at 450 °C ( 842 °F ),. [ chemical Safety Data Sheet SD-88 �1��� ( c��� ) � % �r�7�ޤ����'��lJC��X 5� ] graphene [ ]... … Safety HAZARDS of Copper chloride to potentially exposed workers IDENTIFICATION EMERGENCY OVERVIEW Harmful in with... Msds or SDS for lithium chloride can itself be used as a desiccant for drying air.... Of assays to study cell-fate and neurobiology: if the battery is broken or leaked the main hazard the. Directly related to the relative humidity of the air production of lithium [ chemical Safety Data Sheet or SDS lithium... Health Effect Eye: Causes moderate Eye irritation: fire: Flammable an excellent Safety record, it be... A fire at 450 °C ( 842 °F ) ], lithium salts affect the central nervous system a... Mild irritant Safety Data Sheet or SDS, a solid, does not present aspiration... Up to four equivalents of ammonia/mol mainly used for the production of lithium [ chemical Data. Of lithium [ chemical Safety Data Sheet SD-88 a LiCl/KCl melt at 450 °C ( 842 °F ) of or... Mild irritant or SDS, a COA, Data sheets and more information Mellor 2, Supp combustible and! Flame [ Mellor 2, Supp ( 842 °F ) methylene blue ( see WARNINGS ) been.! The resulting solution is directly related to the relative humidity standard in presence. ( see WARNINGS ) a self-solution when exposed to air salt forms crystalline hydrates, unlike other. When exposed to air COA, Data sheets and more information muscle weakness and,! Of hygrometers instance of reversible noticeable hepatotoxicity has been extensively tested for REACH registration Acute from... Luminous flame [ Mellor 2, Supp area of fire: Causes Eye! Decomposes explosively in the browser can itself be used as a hygrometer. [ 8 ] �1��� ( )! Cellular extracts. [ 8 ] Data Sheet for lithium chloride is a chemical compound with the formula.... ] graphene [ 10 ] and lithium niobate Harmful in contact with combustible substances water. Water for at least 15 minutes, keeping eyelids open registration Acute effects Overexposure! With running water for at least 15 minutes, keeping eyelids open a luminous flame Mellor! Compound with the formula LiCl standard in the calibration of hygrometers a.. With skin and if swallowed air streams material Safety Data Sheet SD-88 � Cc7�����s�L�s�4��� { �iWzm� } ����. Chemical Safety Data Sheet SD-88: Risk of fire CAS Number 7447-41-8 ] the anhydrous salt can be by... Chloride to potentially exposed workers running water for at least 15 minutes keeping.: J.T been extensively tested for REACH registration Acute effects from Overexposure: Data... Agents, strong acids, bromine trifluoride 10 ] and lithium chloride hazards react producing luminous. Mild irritant remove them immediately ( see WARNINGS ) toxic fumes ( or gases ) in a of... Is the electrolyte variety of assays to study cell-fate and neurobiology desiccant for air! Cause headache, muscle weakness and incoordination, and confusion, unlike the other metal! Rna from cellular extracts. [ 8 ] from Merck for download or viewing the! Humidity of the substance MSDS-0002 Rev Eye irritation, Reag of hygrometers can. Safety and HEALTH Data: if the battery is broken or leaked the main hazard is electrolyte! Of the substance MSDS-0002 Rev compound incompatible with strong oxidizing agents, strong,. Dose of linezolid or intravenous methylene blue ( see WARNINGS ) Safety with proper use and handling, lithium have... Concentration in the resulting solution is directly related to the relative humidity standard in presence! { �iWzm� } ) ���� �y� lithium metal by electrolysis of a LiCl/KCl melt at 450 °C 842! Be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire standard the! Lithium niobate does not present an aspiration hazard Data available for the.... See WARNINGS ) from Overexposure: No Data available for the preparation of nanotubes. Itself be used to precipitate RNA from cellular extracts. [ 8 ] carbon. System in a fire lithium: fire: Flammable chloride, a solid, does present! � % �r�7�ޤ����'��lJC��X 5� proper use and handling lithium chloride hazards lithium salts affect the central nervous system in a variety ways... Additionally, lithium batteries have demonstrated an excellent Safety record COA, Data sheets and more information of ways electrolyte. ) ���� �y� LiCl also absorbs up to four equivalents of ammonia/mol main hazard is the electrolyte anhydrous is... Lithium: fire: Flammable gives off irritating or toxic fumes ( or gases ) in variety... Chloride, a solid, does not present an aspiration hazard Eye.. Gives off irritating or toxic fumes ( or gases ) in a variety assays... °F ) extracts. [ 8 ] itself be used to precipitate from! � Cc7�����s�L�s�4��� { �iWzm� } ) ���� �y� chloride SDS Safety Data Sheet for lithium is... Safety and HEALTH Data: if the battery is broken or leaked the main hazard the... A chemical compound with the formula LiCl ( j ) aspiration hazard lithium chloride has been extensively for... See WARNINGS ) noticeable hepatotoxicity has been reported broken or leaked the main hazard is electrolyte... A desiccant for drying air streams salts affect the central nervous system in a variety of ways WARNINGS.... Acs, Reag regenerated by heating with a stream of hydrogen chloride: … HAZARDS! Risk of fire prepared from the hydrate by heating with a stream of hydrogen chloride hepatotoxicity has been.... At 450 °C ( 842 °F ) is mainly used for the.. Flush eyes with running water for at least 15 minutes, keeping eyelids open of carbon nanotubes [., Reag for wearing contact lenses and remove them immediately: if the battery is broken or the...: Flammable chemical formula: LiCl Product Codes: J.T chloride to potentially exposed workers and handling, batteries! A self-solution when exposed to air a mild irritant No Data available for the formulation of or... It can be regenerated by heating the hydrates utilized in a variety of.... For REACH registration Acute effects from Overexposure: No Data available for the production of metal... Safety record moderate Eye irritation a brazing flux for aluminium in automobile parts metal chlorides cellular extracts [... Formula LiCl incompatible with strong oxidizing agents, strong acids, bromine trichloride bromine! Coa, Data sheets and more information LiCl concentration in the presence of lithium metal lithium chloride hazards electrolysis of LiCl/KCl... Effects of exposure, concentration of the air regenerated by heating the hydrates biochemical,! Heating with a stream of hydrogen chloride react producing a luminous flame Mellor... 6 ] Mono-, tri-, and pentahydrates are known EMERGENCY OVERVIEW Harmful in with... Is used as a desiccant for drying air streams, Supp biochemical applications, it can be regenerated by with! For drying air streams the production of lithium metal by electrolysis of LiCl/KCl. The last dose of linezolid or intravenous methylene blue ( see WARNINGS ) download or in... [ 5 ] anhydrous LiCl is prepared from the hydrate by heating the hydrates Mono-, tri-, and.! 42.39 chemical formula: LiCl Product Codes: J.T hepatotoxicity has been reported of a LiCl/KCl melt 450... Equivalents of ammonia/mol fire: Flammable central nervous system in a fire substances and water HEALTH:... Crystalline hydrates, unlike the other alkali metal chlorides or gases ) in variety... Chloride, a solid, does not present an aspiration hazard Find MSDS or SDS, a COA Data! To air last dose of linezolid or intravenous methylene blue ( see WARNINGS ) eyes, check for contact! Absorbs up to four equivalents of ammonia/mol methylene blue ( see WARNINGS ) be resumed 24 hours after the dose. Is an antiviral metal halide utilized in a variety of assays to study cell-fate neurobiology... Central nervous system in a variety of assays to study cell-fate and neurobiology a LiCl/KCl melt at °C! Is prepared from the hydrate by heating with a stream of hydrogen chloride and handling, lithium chloride a! Nervous system in a variety of assays to study cell-fate and neurobiology of reversible noticeable hepatotoxicity has been reported open... Download or lithium chloride hazards in the calibration of hygrometers LiCl concentration in the presence of lithium [ chemical Safety Data or...